This tutorial assumes that you have already opened Outlook Express:
1. Click Tools > Accounts > Mail Tab
2. Click the Account that needs to be changed
3. Click Properties
4. Set the Outgoing / SMTP Mail Server setting needs to be mail.your-domain-name.co.za
5. Tick My server requires authentication
6. Select Settings: ensure that “Use same settings as my incoming mail server” is selected
7. Click OK > Apply > OK
8. Click Restart Outlook Express